1 March 2014
Last updated at 18:11 ET
Acting President Olexander Turchynov said he had also stepped up security at key sites, including nuclear plants.
Russia's Vladimir Putin requested extra troops to protect Russian interests in Ukraine. It came on a day of pro-Russia rallies in the country.
The move has been met with alarm from Western leaders.
President Putin had a 90-minute phone call with US President Barack Obama in which, the Kremlin said, he made clear that Moscow reserves the right to protect its interests and those of Russian speakers in Ukraine.
He also stressed that that this would not be limited to the
current flashpoint of Crimea "if violence spread further in the eastern
regions of Ukraine".
Mr Obama, the White House said, told Mr Putin that the appropriate way to address any concerns "is peacefully through direct engagement" with the Ukrainian government and international mediating bodies.
UN Secretary General Ban Ki-moon has called for "an immediate restoration of calm and direct dialogue", whilst Nato chief Anders Fogh Rasmussen tweeted: "Urgent need for de-escalation in Crimea."
The UN Security Council was holding an emergency session on the crisis on Saturday, and Nato and EU officials are due to hold talks in the coming days.
Ukraine army on full alert as Russia backs sending troops
Ukraine
says it has put its army on full combat alert after Russia's parliament
approved the deployment of Russian troops to Ukraine.
Russia's Vladimir Putin requested extra troops to protect Russian interests in Ukraine. It came on a day of pro-Russia rallies in the country.
The move has been met with alarm from Western leaders.
President Putin had a 90-minute phone call with US President Barack Obama in which, the Kremlin said, he made clear that Moscow reserves the right to protect its interests and those of Russian speakers in Ukraine.
Mr Obama, the White House said, told Mr Putin that the appropriate way to address any concerns "is peacefully through direct engagement" with the Ukrainian government and international mediating bodies.
UN Secretary General Ban Ki-moon has called for "an immediate restoration of calm and direct dialogue", whilst Nato chief Anders Fogh Rasmussen tweeted: "Urgent need for de-escalation in Crimea."
The UN Security Council was holding an emergency session on the crisis on Saturday, and Nato and EU officials are due to hold talks in the coming days.
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Bloody scuffles"The facts on the ground are such that Russia, to a large extent, is already in control there ”
In his live television address,
President Turchynov urged Ukrainians to bridge divisions in the country
and said they must not fall for provocations.
But tensions are high, not only in Crimea which is home to a large number of ethnic Russians.
There were big pro-Russian rallies in several Ukrainian cities on Saturday.
In Kharkiv, Ukraine's second-biggest city, dozens of people were injured after scuffles between pro- and anti-Russian protesters broke out outside the regional administration building.
In Mariupol, in the south-east, hundreds of protesters carrying Russian flags gathered outside the city council.
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Crimea
- Autonomous republic within Ukraine
- Transferred from Russia in 1954
- Ethnic Russians - 58.5%*
- Ethnic Ukrainians - 24.4%*
- Crimean Tatars - 12.1%*
- Source: Ukraine census 2001
President Putin submitted the
request for troops "in connection with the extraordinary situation in
Ukraine and the threat to the lives of Russian citizens", the Kremlin
said.
Deputy Foreign Minister Grigory Karasin said, however, that this "does not mean that this right will be used quickly" to deploy troops.
During the upper house debate, one legislator accused President Obama of crossing "a red line" with his comments on Friday that there would be "costs" if Russia intervened militarily in Ukraine.
The upper house has recommended that the Russian ambassador to the US should be recalled, although the decision lies with Mr Putin.
Despite the political developments on Saturday, observers have been watching a build up of Russian military activity in Crimea - home to Russia's Black Sea Fleet - for the past few days.
Latest reports say two Russian anti-submarine warships have appeared off the coast of Crimea in violation of an agreement governing the presence of Russia's Fleet in the peninsula.
Russian soldiers are widely reported to be guarding a number of administrative buildings and military bases in Crimea. Parliament, airports, the state television building and telecommunications hubs have also been surrounded.
Some 6,000 extra Russian troops and 30 additional armoured vehicles are now in Crimea, Ukrainian Defence Minister Ihor Tenyukh said earlier on Saturday.
The newly-elected pro-Moscow leader of Crimea, Sergiy Aksyonov, said he had appealed to Mr Putin for help to ensure peace on the peninsula.
The interim government in Kiev does not recognise Mr Aksyonov and his government, and signed a decree on Saturday that their election at an emergency session of the regional parliament this week was illegal.
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