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New research could lead to more efficient electrical energy storage

Date:

March 4, 2015

Source:

DOE/Lawrence Livermore National Laboratory

Summary:

Researchers have identified electrical charge-induced changes in the structure and bonding of graphitic carbon electrodes that may one day affect the way energy is stored. The research could lead to an improvement in the capacity and efficiency of electrical energy storage systems, such as batteries and supercapacitors, needed to meet the burgeoning demands of consumer, industrial and green technologies.

Lawrence Livermore research has opened a new window toward more efficient electrochemical energy storage systems.

Credit: Illustration by Ryan Chen/LLNL

[Click to enlarge image]

Lawrence Livermore researchers have identified electrical charge-induced changes in the structure and bonding of graphitic carbon electrodes that may one day affect the way energy is stored.

The research could lead to an improvement in the capacity and efficiency of electrical energy storage systems, such as batteries and supercapacitors, needed to meet the burgeoning demands of consumer, industrial and green technologies.

Future technology requires energy storage systems to have much larger storage capability, rapid charge/discharge cycling and improved endurance. Progress in these areas demands a more complete understanding of energy storage processes from atomic through micron-length scales. Because these complex processes can change significantly as the system is charged and discharged, researchers have increasingly focused on how to look inside an operating energy storage system. While computational approaches have advanced over the last few decades, the development of experimental approaches has been very challenging, particularly for studying the light elements that are prevalent in energy storage materials.

Recent work by an LLNL-led team developed a new X-ray adsorption spectroscopy capability that is tightly coupled with a modeling effort to provide key information about how the structure and bonding of graphitic carbon supercapacitor electrodes are affected by polarization of the electrode -- electrolyte interfaces during charging.

Graphitic supercapacitors are ideal model systems to probe interfacial phenomena because they are relatively chemically stable, extensively characterized experimentally and theoretically and are interesting technologically. The team used its recently developed 3D nanographene (3D-NG) bulk electrode material as a model graphitic material.

"Our newly developed X-ray adsorption spectroscopy capability allowed us to detect the complex, electric-field induced changes in electronic structure that graphene-based supercapacitor electrodes undergo during operation. Analysis of these changes provided information on how the structure and bonding of the electrodes evolve during charging and discharging," said Jonathan Lee, an LLNL scientist and corresponding author of a paper scheduled to appear as the cover article of the March 4 edition of the journal, Advanced Materials. "The integration of unique modeling capabilities for studying the charged electrode-electrolyte interface played a crucial role in our interpretation of the experimental data."

Discovering that the electronic structure of graphitic carbon supercapacitor electrodes can be tailored by charge-induced electrode-electrolyte interactions opens a new window toward more efficient electrochemical energy storage systems. In addition, the experimental and modeling techniques developed during the research are readily applicable to other energy storage materials and technologies.

Story Source:

The above story is based on materials provided by DOE/Lawrence Livermore National Laboratory. Note: Materials may be edited for content and length.

Journal Reference:

Michael Bagge-Hansen, Brandon C. Wood, Tadashi Ogitsu, Trevor M. Willey, Ich C. Tran, Arne Wittstock, Monika M. Biener, Matthew D. Merrill, Marcus A. Worsley, Minoru Otani, Cheng-Hao Chuang, David Prendergast, Jinghua Guo, Theodore F. Baumann, Tony van Buuren, Jürgen Biener, Jonathan R. I. Lee. Supercapacitors: Potential-Induced Electronic Structure Changes in Supercapacitor Electrodes Observed by In Operando Soft X-Ray Spectroscopy (Adv. Mater. 9/2015). Advanced Materials, 2015; 27 (9): 1469 DOI: 10.1002/adma.201570057

Cite This Page:

DOE/Lawrence Livermore National Laboratory. "New research could lead to more efficient electrical energy storage." ScienceDaily. ScienceDaily, 4 March 2015. .

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